Photocontrolled Ring‐Opening Polymerization of Strained Dicarba[2]Ferrocenophanes: A Route to Well‐Defined Polyferrocenylethylene Homopolymers and Block Copolymers |
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| Authors: | David?E Herbert Ulrich?F?J Mayer Joe?B Gilroy Dr María?J López‐Gómez Alan?J Lough Dr Jonathan?P?H Charmant Dr Ian Manners Prof |
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| Institution: | 1. School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS (UK), Fax: (+44)?117‐929‐0509;2. X‐ray Crystallography, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, M5S 3H6 (Canada) |
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| Abstract: | The ring‐opening polymerization (ROP) behavior of a variety of substituted 1,1′‐ethylenylferrocenes, or dicarba2]ferrocenophanes, is reported. The electronic absorption spectra and tilted solid‐state structures of the monomers rac‐Fe(η5‐C5H4)2(CHiPr)2] ( 7 ), Fe(η5‐C5H4)2(C(H)MeCH2)] ( 8 ), and rac‐Fe(η5‐C5H4)2(CHPh)2] ( 9 ) are consistent with the presence of substantial ring strain, which was exploited to synthesize soluble, well‐defined polyferrocenylethylenes (PFEs) Fe(η5‐C5H4)2(C(H)MeCH2)]n ( 12 ) and Fe(η5‐C5H4)2(CHPh)2]n ( 13 ) through photocontrolled ROP. Polymer chain lengths could be controlled by the monomer‐to‐initiator ratio up to about 50 repeat units and, consistent with the “living” nature of the polymerizations, sequential block copolymerization with a sila1]ferrocenophane led to polyferrocenylethylene–polyferrocenylsilane (PFE‐b‐PFS) block copolymers ( 14 and 15 ). PFE polymers 12 and 13 showed two reversible oxidation waves, indicative of appreciable Fe???Fe interactions along the polymer backbone. The diblock copolymers were characterized by NMR spectroscopy, GPC analysis, and cyclic voltammetry. |
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| Keywords: | inorganic polymers metallopolymers metal– metal interactions polymerization |
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