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Synthesis,Characterization, and Electro‐Optical Properties of ZnII Complexes with π‐Conjugated Terpyridine Ligands |
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| Authors: | Andreas Winter Dr. Christian Friebe Manuela Chiper Dr. Ulrich S. Schubert Prof. Dr. Martin Presselt Benjamin Dietzek Dr. Michael Schmitt Dr. Jürgen Popp Prof. Dr. |
| Affiliation: | 1. Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven (The Netherlands);2. Laboratory of Organic and Macromolecular Chemistry, Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena (Germany), Fax: (+49)?3641‐948202;3. Institute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, 07743 Jena (Germany), Fax: (+49)?3641‐948320;4. Institute of Photonic Technology, Albert Einstein Str. 9, 07745 Jena (Germany) |
| Abstract: | Leading light : A series of zinc(II) bis‐terpyridine complexes (see picture) is investigated by means of DFT calculations combined with Bader's quantum theory of atoms in molecules. Raman spectroscopy experiments and studies of the electro‐optical properties of the complexes in solution and the solid state are also performed to examine their potential as new emissive materials in light‐emitting devices.  |
| Keywords: | coordination chemistry density functional calculations Raman spectroscopy terpyridines zinc |