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A Waterwheel‐Shaped meso–meso‐Linked Porphyrin Pentamer
Authors:Chieh‐Ao Wu  Chien‐Lan Chiu  Chi‐Lun Mai Dr.  You‐Shiang Lin  Chen‐Yu Yeh Prof.
Affiliation:Department of Chemistry, National Chung Hsing University, Taichung 402 (Taiwan), Fax: (+886)?4‐2286‐2547
Abstract:Wheels on water? A waterwheel‐shaped porphyrin pentamer has been synthesized by palladium‐catalyzed cross‐coupling reactions. The key intermediate is a boronate porphyrin, in which four boronic ester groups are directly attached to the meso‐positions.
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Keywords:cross‐coupling  electrochemistry  molecular electronics  oxidation  porphyrinoids
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