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Synthesis,Properties and Formation of (RCp)Co‐ and (RCp)Rh‐Stabilized[4.8]3Cyclacene Derivatives
Authors:Stefan?C Kornmayer Dr  Björn Hellbach Dr  Frank Rominger Dr  Rolf Gleiter Prof?Dr
Institution:Organisch‐Chemisches Institut, Universit?t Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg (Germany), Fax: (+49)?6221‐544‐205
Abstract:Metal‐stabilized belts : A torus, 3 , consisting of three four‐ and three eight‐membered conjugated rings and stabilized by (RCp)Co‐ and (RCp)Rh‐ units, was generated by irradiation of (RCp)Co(CO)2] and (RCp)Rh(C2H4)2], respectively, and 1 .
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Keywords:alkyne dimerization  conjugation  cyclacenes  cyclobutadiene  torus
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