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Palladium‐Catalyzed Intramolecular Hydroamination of Allenes Coupled to Aerobic Alcohol Oxidation |
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| Authors: | Shuifa Qiu Yunyang Wei Prof. Dr. Guosheng Liu Prof. Dr. |
| Affiliation: | 1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academic of Science, 354 Fengling Road, Shanghai, 200032 (China), Fax: (+86)?21‐64166128;2. Department School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaoling wei, Nanjing, 200094 (China) |
| Abstract: | Taking the air! A PdII‐catalyzed intramolecular hydroamination of allenes coupled to alcohol oxidation has been developed. This reaction is performed by using a nitrogen‐based ligand under aerobic conditions, under which the molecular oxygen is used as the terminal oxidant for the reoxidation of Pd0 species to complete the catalytic cycle.  |
| Keywords: | alcohols allenes hydroamination aerobic oxidation palladium |