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Trapping Reactive Metal–Carbene Complexes by a Bis‐Pocket Porphyrin: X‐ray Crystal Structures of RuCHCO2Et and trans‐[Ru(CHR)(CO)] Species and Highly Selective Carbenoid Transfer Reactions
Authors:Qing‐Hai Deng  Jian Chen Dr  Jie‐Sheng Huang Dr  Stephen Sin‐Yin Chui Dr  Nianyong Zhu Dr  Guang‐Yu Li  Chi‐Ming Che Prof Dr
Institution:1. Shanghai‐Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, The Chinese Academy of Sciences, 354 Feng Lin Road, Shanghai 200032 (China), Fax: (+852)?28571586;2. Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road (Hong Kong)
Abstract:
Keywords:carbenoids  porphyrinoids  reactive intermediates  ruthenium  structure elucidation
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