1. Institut für Anorganische Chemie der Universit?t Regensburg, 93040 Regensburg (Germany), Fax: (+49)?941‐943‐4439;2. Sciences Chimiques de Rennes, UMR 6226 CNRS‐Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex (France), Fax: (+33)?223‐23‐69‐39;3. Nikolaev Institute of Inorganic Chemistry, Siberian Division of RAS, Acad. Lavrentyev prosp. 3, 630090 Novosibirsk (Russia)
Abstract:
Bridging ligands in AgI and AuI bimetallic complexes: The P moiety of bis(2‐pyridyl)phosphole acts as a symmetrically, semi‐, or non‐bridging donor in AgI dimers (see figure). In related AuI complexes, only the non‐bridging mode is observed. An unsaturated AgI dimer is used as an adaptive molecular clip for the synthesis of π‐stacked metallocyclophanes.
