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A Novel Tripodal Ligand Containing Three Different N‐Heterocyclic Donor Functions and Its Application in Catechol Dioxygenase Mimicking
Authors:Marit Wagner Dipl‐Chem  Christian Limberg Prof Dr  Thomas Tietz Dipl‐Chem
Institution:Institut für Anorganische Chemie, Humboldt‐Universit?t zu Berlin, Brook‐Taylor‐Str. 2, 12489 Berlin (Germany), Fax: (+49)?030‐2093‐6966
Abstract:Prominent donors : A pyridyl, an imidazolyl, and a pyrazolyl donor function are part of the novel tripodal ligand depicted, which thus combines three of the most prominent donors applied in ligands for bioinorganic chemistry within one coordination unit. To exploit its behaviour and potential, first investigations have been carried out in relation to catechol dioxygenase mimicry.
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Keywords:coordination modes  iron  N ligands  O?O activation  reaction mechanisms
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