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Synthesis,Electronic Properties,and Reactivity of Phospholes and 1,1′‐Biphospholes Bearing 2‐ or 3‐Thienyl C‐Substituents
Authors:Omrane Fadhel Dr  Dénes Szieberth Dr  Valérie Deborde  Christophe Lescop Dr  László Nyulászi Prof  Muriel Hissler Prof  Régis Réau Prof
Institution:1. Sciences Chimiques de Rennes, UMR 6226 CNRS‐Université de Rennes 1, Campus de beaulieu, 35042 Rennes Cedex (France), Fax: (+33)?2‐23‐23‐69‐39;2. Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Gellért tér 4, 1111 Budapest (Hungary)
Abstract:PS, I love you! Novel mixed phosphole/thiophene π‐conjugated systems were synthesized and their electronic properties have been studied both experimentally by UV/Vis spectroscopy and electrochemistry and by theoretical calculations. Exploiting the chemistry of both P‐ and S‐heteroles allows the generation of a diverse range of novel ring‐fused benzophosphole–thiophene derivatives.
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Keywords:density functional calculations  phospholes  photocyclization  thiophenes  pi interactions
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