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Nano‐Supramolecular Assemblies Constructed from Water‐Soluble Bis(calix[5]arenes) with Porphyrins and Their Photoinduced Electron Transfer Properties
Authors:Dong‐Sheng Guo Dr.  Kun Chen  Hong‐Qing Zhang  Yu Liu Prof. Dr.
Affiliation:Department of Chemistry, State Key Laboratory of Elemento‐Organic Chemistry, Nankai University, Tianjin, 300071 (P.R. China), Fax: (+86)?22‐2350‐3625
Abstract:What a PET! Two well‐defined nanoarchitectures with 2D netlike and 1D linear topological structures are constructed by bis(p‐sulfonatocalix[5]arenes) and cationic porphyrins, respectively, in which an unambiguous PET process is observed. As a result, the supramolecular aggregates possess, in principle, benign photoelectric properties with the transport of an electron between the building blocks in the nanoscale region.
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Keywords:calixarenes  electron transfer  inclusion compounds  porphyrin  supramolecular chemistry
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