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Host‐Assisted Guest Self‐Assembly: Enhancement of the Dimerization of Pyronines Y and B by γ‐Cyclodextrin
Authors:Jorge Bordello  Belén Reija Dr.  Wajih Al‐Soufi Prof. Dr.  Mercedes Novo Prof. Dr.
Affiliation:Grupo de Fotofísica e Fotoquímica Molecular, Departamento de Química Física, Facultade de Ciencias, Universidade de Santiago de Compostela, 27002 Lugo (Spain), Fax: (+34)?982‐285‐872
Abstract:Buckle up! The dimerization of small fluorescent guests is strongly enhanced in presence of a cyclodextrin host. The host cavity acts like a belt to assist the self‐assembly of guests (see picture). Small variations in the guest structure have significant influence on the stability and geometry of the aggregates.
image

Keywords:cyclodextrins  host–  guest systems  pyronines  supramolecular chemistry  UV/Vis spectroscopy
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