Charge‐Separated and Molecular Heterobimetallic Rare Earth–Rare Earth and Alkaline Earth–Rare Earth Aryloxo Complexes Featuring Intramolecular Metal–π‐arene Interactions期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Charge‐Separated and Molecular Heterobimetallic Rare Earth–Rare Earth and Alkaline Earth–Rare Earth Aryloxo Complexes Featuring Intramolecular Metal–π‐arene Interactions

Authors:	Glen B Deacon Prof Dr Peter C Junk Prof Dr Graeme J Moxey Karin Ruhlandt‐Senge Prof Dr Courtney St Prix Dr Maria F Zuniga Dr

Institution:	1. School of Chemistry, Monash University, Clayton, VIC 3800 (Australia), Fax: (+61)?399054597;2. Department of Chemistry, 1‐014 Center for Science and Technology, Syracuse University, Syracuse, NY 13244‐4100 (USA), Fax: (+1)?315‐443‐4070

Abstract:	A new family in town! Treatment of a rare‐earth metal (Ln) and either a potential divalent rare‐earth metal (Ln′) or an alkaline earth metal (Ae) with 2,6‐diphenylphenol (HOdpp) at elevated temperatures (200–250 °C) afforded heterobimetallic aryloxo complexes (see figure). Both a charge‐separated species, (Ln′/Ae)₂(Odpp)₃]Ln(Odpp)₄], and a neutral species, AeEu(Odpp)₄], were obtained and crystallographically characterised.

Keywords:	alkaline earth metals heterobimetallic complexes O ligands pi interactions rare earths