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Structure Formation Principles and Reactivity of Organolithium Compounds |
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| Authors: | Viktoria H Gessner Christian Däschlein Carsten Strohmann Prof Dr |
| Institution: | Anorganische Chemie, Technische Universit?t Dortmund, Otto‐Hahn‐Strasse 6, 44227 Dortmund (Germany), Fax: (+49)?231‐755‐7062 |
| Abstract: | Organolithium chemistry! An overview of the structure formation principles and the strong structure–reactivity relationship of lithium organics is given. By means of the commonly used lithium bases the deaggregation of the oligomeric parent structures to small adducts is presented (see examples) and compared to the related chemistry of lithiosilanes.  |
| Keywords: | alkyllithium compounds N ligands silyllithium compounds structure– activity relationships structure elucidation |