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Magnetic Bistability of Individual Single‐Molecule Magnets Grafted on Single‐Wall Carbon Nanotubes
Authors:Anna Giusti Dr.  Gaëlle Charron Dr.  Sandra Mazerat  Jean‐Daniel Compain  Pierre Mialane Prof.  Anne Dolbecq Dr.  Eric Rivière Dr.  Wolfgang Wernsdorfer Dr.  Rosa Ngo Biboum  Bineta Keita Dr.  Louis Nadjo Prof.  Arianna Filoramo Dr.  Jean‐Philippe Bourgoin Dr.  Talal Mallah Prof.
Affiliation:1. Institut de Chimie Moléculaire et des Matériaux d'Orsay, Université Paris‐Sud 11, CNRS UMR 8182, 91405 Orsay (France), Fax: (+33)?1‐6915‐4754;2. Institut Lavoisier de Versailles (France);3. Institut Néel, Grenoble (France);4. Laboratoire de Chimie Physique, Orsay (France);5. Laboratoire d'Electronique Moléculaire, CNRS, Gif sur Yvette (France)
Abstract:A POM to remember : Hexanuclear FeIII polyoxometalate (POM) single‐molecule magnets (see structure) can be noncovalently assembled on the surface of single‐wall carbon nanotubes. Complementary characterization techniques (see TEM image and magnetic hysteresis loops) demonstrate the integrity and bistability of the individual molecules, which could be used to construct single‐molecule memory devices.
image

Keywords:iron  magnetic properties  nanotubes  polyoxometalates  single‐molecule magnets
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