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Synthesis,Structure and Reactivity of Disila‐ and Distanna ansa Half‐Sandwich Complexes of Molybdenum and Tungsten |
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| Authors: | Holger Bera Dr. Holger Braunschweig Prof. Dr. Rainer Dörfler Kai Hammond Andreas Oechsner Krzysztof Radacki Dr. Katharina Uttinger Dr. |
| Affiliation: | Julius‐Maximilians‐Universit?t Würzburg, Am Hubland, 97074 Würzburg (Germany), Fax: (+49)?931‐888‐4623 |
| Abstract: | We present the synthesis and characterization of disila‐ and distanna ansa half‐sandwich complexes of Group 6 transition metals. These compounds exhibit high ring strain within the ansa bridge, which is the key factor for the insertion of elemental chalcogens. |
| Keywords: | chalcogens half‐sandwich complexes insertion molybdenum tungsten |