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Bottom‐Up Synthesis of Porous Coordination Frameworks: Apical Substitution of a Pentanuclear Tetrahedral Precursor |
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| Authors: | Xin‐Long Wang Prof. Chao Qin Prof. Shui‐Xing Wu Dr. Kui‐Zhan Shao Dr. Ya‐Qian Lan Dr. Shuang Wang Dr. Dong‐Xia Zhu Prof. Zhong‐Min Su Prof. En‐Bo Wang Prof. |
| Affiliation: | Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China) |
| Abstract: | Top down goes bottom up : A family of microporous interpenetrating diamond frameworks can be constructed from a pentanuclear tetrahedral complex with nitrate groups at the apical positions as an inorganic precursor. A “bottom‐up” methodology was used for substitution of the nitrate groups by linear ditopic carboxylate ligands (see picture). The Langmuir surface area of the resulting frameworks is higher than that of classical zeolites.  |
| Keywords: | adsorption interpenetrating networks metal– organic frameworks microporous materials zinc |