1. Research School of Chemistry, Australian National University, Canberra, ACT 0200 (Australia), Fax: (+61)?2‐6125‐8114;2. ARC Centre of Excellence for Free Radical Chemistry and Biotechnology (Australia);3. Correspondence author for crystallographic data
Abstract:
Guest‐love‐ometer : The equilibrium inside–outside atropisomeric ratio of ortho‐substituted phenyl cavitands shows a strong solvent dependence. The competition between the ortho‐substituent and the solvent guest for the bowl cavity leads to a sensitive system for the measurement of relative guest binding affinities.
