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Infrared Absorption Spectra of t‐HNOH Radicals Generated on VUV Irradiation of NO in Solid Hydrogen
Authors:Yu‐Jong Wu Dr  Meng‐Yeh Lin  Sheng‐Chuan Hsu  Bing‐Ming Cheng Dr
Institution:National Synchrotron Radiation Research Center, 101 Hsin‐Ann Road, Hsinchu Science Park, Hsinchu 30076 (Taiwan), Fax: (+886)?3‐5783813
Abstract:Photoproduct signature: Irradiation of solid hydrogen near 3 K containing NO with vacuum‐UV light from synchrotron radiation yields new infrared absorption lines at 1241.7, 1063.6 and 726.2 cm?1 (see figure). These new lines are assigned to vibrational modes of t‐HNOH. This photoproduct is formed from electronically excited NO reacting with neighboring hydrogen in the solid sample.
image

Keywords:condensed phase  density functional calculations  hydrogen  IR spectroscopy  vibrational modes
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