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ScIII‐Doped Zeolites as New Heterogeneous Catalysts: Mukaiyama Aldol Reaction
Authors:Andrea Olmos  Aurélien Alix  Jean Sommer Prof. Dr.  Patrick Pale Prof. Dr.
Affiliation:1. Laboratoire de Physicochimie des Hydrocarbures, Institut de Chimie de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg (France);2. Laboratoire de Synthèse et Réactivité Organiques, Institut de Chimie de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg (France)
Abstract:ScIII‐doped solids based on zeolite materials have been investigated for the first time as catalysts in organic synthesis. ScIII–USY zeolite proved to be a novel and very efficient heterogeneous catalyst for the Mukaiyama aldol reaction. This easy‐to‐prepare catalyst exhibited wide scope and compatibility with functional groups and is very simple to use, easy to remove (by simple filtration), and is recyclable (up to three times without loss of activity).
Keywords:aldol reaction  heterogeneous catalysis  scandium  zeolites
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