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Self‐Assembly of High‐Nuclearity Copper Cages: Tricorne Cu21 and Saddlelike Cyclic Cu16 |
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| Authors: | Yue‐Ling Bai Vassilis Tangoulis Prof. Rong‐Bin Huang Prof. Lan‐Sun Zheng Prof. Dr. Jun Tao Prof. Dr. |
| Affiliation: | 1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (P.R. China), Fax: (+86)?592‐218‐3047;2. Laboratory of Inorganic Chemistry, Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54124 (Greece), Fax: (+30)?2310997738 |
| Abstract: | Copper clusters : Two high‐nuclearity copper cages, tricorne Cu21 and saddlelike cyclic Cu16 (see pictures), were synthesized. Magnetic studies and Monte Carlo calculations were also performed to show the overall antiferromagnetic properties of the two compounds.  |
| Keywords: | ab initio calculations azides copper magnetic properties metallocages |