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Robust Supramolecular Network on Ag(111): Hydrogen‐Bond Enhancement through Partial Alcohol Dehydrogenation |
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| Authors: | Remy Pawlak Sylvain Clair Dr Vincent Oison Dr Mathieu Abel Dr Oualid Ourdjini Nikolas A A Zwaneveld Dr Didier Gigmes Dr Denis Bertin Prof Laurent Nony Dr Louis Porte Prof |
| Institution: | 1. Aix‐Marseille Université, Institut Matériaux, Microélectronique et Nanosciences de Provence, CNRS UMR 6242, Campus de Saint‐Jér?me, Case 142, 13397 Marseille Cedex (France), Fax: (+33)?491‐282859;2. Aix‐Marseille Université, Laboratoire Chimie Provence, CNRS UMR 6264, Campus de Saint‐Jér?me, Case 542, 13397 Marseille Cedex (France) |
| Abstract: | Alcohol oxidation and self‐assembly: the in situ oxidation of hydroxyl functional groups to quinone groups promotes the formation of enhanced hydrogen bonds and allows reorganization of the resulting supramolecular self‐assemblies, which evolve from a weakly bound dense phase to a strongly bound nanoporous open structure (see picture).  |
| Keywords: | alcohols dehydrogenation quinones scanning tunneling microscopy supramolecular chemistry |