Electrochemical Detection of Hydrazine Based on Electrospun Palladium Nanoparticle/Carbon Nanofibers |
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Authors: | Haijiang Zhang Jianshe Huang Haoqing Hou Tianyan You |
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Institution: | 1. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, P.?R. China;2. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330027, P.?R. China |
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Abstract: | In this work, we developed an electrochemical method for the detection of hydrazine based on palladium nanoparticle/carbon nanofibers (Pd/CNFs). Pd/CNFs were prepared by electrospinning technique and subsequent thermal treatments. The electrocatalytic behaviors of Pd/CNFs modified glassy carbon electrode (Pd/CNF‐GCE) for hydrazine oxidation were evaluated by cyclic voltammetry (CV), an obvious and well‐defined oxidation peak appeared at ?0.32 V (vs. Ag/AgCl). The mechanism of the oxidation of hydrazine at Pd/CNF‐GCE was also studied, which demonstrated an irreversible diffusion‐controlled electrode process and a four‐electron transfer involved in the overall reaction. Furthermore, the wide linear range, low detection limit, good reproducibility and excellent storage stability were obtained utilizing differential pulse voltammetry (DPV). |
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Keywords: | Electrospinning Palladium nanoparticle/carbon nanofibers Electrocatalyst Hydrazine oxidation Ultralow detection potential Nanoparticles Palladium |
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