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UV/Vis to NIR Photoconduction in Cyclopalladated Complexes
Authors:Nicolas Godbert  Davide Dattilo  Roberto Termine  Iolinda Aiello  Anna Bellusci  Alessandra Crispini  Attilio Golemme  Mauro Ghedini
Abstract:Funky discotics : Photoconductivity is measured in newly synthesized cyclopalladated metallomesogens exhibiting hexagonal columnar mesophases at room temperature. The tuning of the HOMO/LUMO energy levels by modification of the chain/core linkage (ester 1 vs ether 2 ) makes compound 2 photoconductive across the whole UV/Vis/NIR range.
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Keywords:liquid crystals  metallomesogens  molecular materials  palladium  photoconduction
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