Redox self-sufficient biocatalyst network for the amination of primary alcohols |
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| Authors: | Johann H Sattler Michael Fuchs Katharina Tauber Francesco G Mutti Kurt Faber Jan Pfeffer Thomas Haas Wolfgang Kroutil |
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| Affiliation: | Department of Chemistry, Organic and Bioorganic Chemistry, University of Graz, Heinrichstrasse 28, 8010 Graz (Austria). |
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| Abstract: | Driving the machinery: A biocatalytic redox-neutral cascade for the preparation of terminal primary amines from primary alcohols at the expense of ammonia has been established in a one-pot one-step method. Applying this artificial biocatalyst network, long-chain 1,ω-alkanediols were converted into diamines, which are building blocks for polymers, in up to 99?% conversion. |
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| Keywords: | alcohols amination biocatalysis polymers |
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