|
|||||
|
|
Room-Temperature Photoinduced Electron Transfer in a Prussian Blue Analogue under Hydrostatic Pressure |
|
| Authors: | Jean-Daniel Cafun Julien Lejeune François Baudelet Paul Dumas Jean-Paul Itié Anne Bleuzen |
| Institution: | Université Paris-Sud, Institut de Chimie Moléculaire et des Matériaux d'Orsay-UMR 8182, Laboratoire de Chimie Inorganique, 91405 Orsay (France); Synchrotron Soleil, L'Orme des Merisiers, St Aubin, 91192 Gif-sur-Yvette (France). |
| Abstract: | In from the cold: The Co(III) Fe(II) state of a CoFe Prussian blue analogue undergoes a Co(III) ?Fe(II) →(Co(II) ?Fe(III) )* electron transfer at room temperature when irradiated by visible light (532?nm; see scheme). This property was confirmed using energy-dispersive X-ray absorption spectroscopy at the Co and Fe K-edges of the piezo-induced Co(III) Fe(II) state. |
| Keywords: | electron transfer magnetic properties Prussian blue spin crossover switchable solid |
| 本文献已被 PubMed 等数据库收录！ | |