Catalytic Hydrogen Atom Transfer (HAT) for Sustainable and Diastereoselective Radical Reduction |
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| Authors: | Andreas Gansäuer Max Klatte Gerhard M Brändle Joachim Friedrich |
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| Affiliation: | 1. Kekulé‐Institut für Organische Chemie und Biochemie der Universit?t Bonn, Gerhard‐Domagk‐Strasse 1, 53121 Bonn (Germany);2. Institut für Chemie, Technische Universit?t Chemnitz, Strasse der Nationen 62, 09111 Chemnitz (Germany) |
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| Abstract: | Going cyclic! A catalytic cycle and cyclic transition states enable a novel sustainable and catalytic hydrogen atom transfer (HAT) for highly diastereoselective radical reductions. Readily available nontoxic silanes are the terminal reductants for epoxides that are opened by bifunctional titanocene(III) hydride catalysts. |
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| Keywords: | homogeneous catalysis hydrogen atom transfer radicals stereoselectivity titanium |
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