A series of isoreticular, highly stable, porous zirconium oxide based metal-organic frameworks |
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| Authors: | V Guillerm F Ragon M Dan-Hardi T Devic M Vishnuvarthan B Campo A Vimont G Clet Q Yang G Maurin G Férey A Vittadini S Gross Christian Serre |
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| Institution: | Institut Lavoisier,UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles (France). |
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| Abstract: | Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr?blue polyhedra, O?red, C?black). They have a one-dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts. |
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| Keywords: | infrared spectroscopy metal–organic framework modeling studies stability zirconium |
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