Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes |
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| Authors: | Taniguchi Tsuyoshi Idota Atsushi Ishibashi Hiroyuki |
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| Affiliation: | School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. tsuyoshi@p.kanazawa-u.ac.jp |
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| Abstract: | Generation of sulfonyl radicals from sulfonylhydrazides has been achieved in the presence of a non-toxic iron catalyst and oxygen. The intermolecular addition of resultant sulfonyl radicals to alkenes affords β-hydroxysulfone compounds. |
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