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Electrochemical oxidative ring opening of 1-methylcyclobutanol |
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| Authors: | N I Kapustina L L Sokova G I Nikishin |
| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
| Abstract: | The manganese(III) acetate-mediated electrooxidative ring opening of 1-methylcyclobutanol (1) in acetic acid affords pentane-2-one (2) as the major product. The reaction of 1-methylcyclobutanol with Mn(OAc)3-LiCl gives 5-chloropentane-2-one (4.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1306–1307, May, 1996 |
| Keywords: | 1-methylcyclobutanol manganese(III) acetate electrochemical oxidation pentane-2-one 5-chloropentane-2-one |
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