|
|||||
|
|
Photochemical rearrangement of 8-oxabicyclo[3.2.1]oct-6-en-2-ones |
|
| Authors: | Albert Padwa Glen E. Fryxell Lin Zhi Susan F. Hornbuckle |
| Affiliation: | Department of Chemistry, Emory University Atlanta, GA 30322 U.S.A. |
| Abstract: | Irradiation of 8-oxabicyclo[3.2.1]oct-6-en-2-ones results in a 1,3-acyl rearrangement. The initial photoproduct undergoes a subsequent reaction involving hydrogen transfer followed by intramolecular cycloaddition of a ketene intermediate. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |