Synthesis and X-ray crystal structures of the first antimony and bismuth calixarene complexes |
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| Authors: | Liu Lihua Zakharov Lev N Rheingold Arnold L Hanna Tracy A |
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| Affiliation: | Department of Chemistry, Texas Christian University, Fort Worth 76129, USA. |
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| Abstract: | The reaction of the monosodium salt of p-tert-butylcalix[4]arene (But)C4) with 2 equivalents of SbCl3 provides ButC4(SbCl)2 and the first bismuth calixarene complex was prepared by treatment of p-tert-butylcalix[8]arene (ButC8) with Bi[N(SiMe3)2]3 in toluene. |
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