Hydrothermal synthesis and characterisation of new methylenediphosphonates of molybdenum(VI), A[MoO2(O3PCH2PO3H)] (A = Rb, NH4 and Tl) |
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| Authors: | M. P. Minimol K. Prabhakara Rao Y. Ram Sai K. Vidyasagar |
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| Affiliation: | (1) Department of Chemistry, Indian Institute of Technology Madras, 600 036 Chennai, India |
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| Abstract: | Three new, isostructural methylenediphosphonates of molybdenum, A[MoO2(O3PCH2PO3H)] (A = Rb (1), NH4 (2) and Tl (3)) have been synthesized by hydrothermal method and structurally characterised by X-ray diffraction and spectroscopic techniques. These compounds crystallize in monoclinic space group,P2 1 /c with Z = 4 and consist of [MoO2(O3PCH2PO3H)]-anionic layers interleaved with A+ ions. Dedicated to Professor C N R Rao on his 70th birthday |
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| Keywords: | Metal diphosphonate hydrothermal synthesis layered structure X-ray diffraction |
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