| 基于半刚性双(噻唑基苯并咪唑)和不同羧酸的五个一维配合物的合成和表征 |
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| 引用本文： | 刘露,靳平宁,李英,娄慧慧,王键吉,张裕平,侯红卫,杜锦阁. 基于半刚性双(噻唑基苯并咪唑)和不同羧酸的五个一维配合物的合成和表征[J]. 无机化学学报, 2019, 35(6): 1076-1084 |
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| 作者姓名： | 刘露 靳平宁 李英 娄慧慧 王键吉 张裕平 侯红卫 杜锦阁 |
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| 作者单位： | 河南科技学院化学化工学院;新乡医学院;河南师范大学化学化工学院;郑州大学化学与分子工程学院;新乡医学院三全学院 |
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| 基金项目： | 河南科技学院高层次人才科研启动项目，河南师范大学博士后科研项目，河南省博士后科研项目，河南省高等学校重点科研项目（No.16A150007），河南省高等学校重点科研项目（No.16A150060）和河南科技学院标志性创新工程项目（No.2015BZ02）资助。 |
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| 摘 要： | 通过水热或溶剂热合成的方法制备了5个一维配合物{[Zn(btbb)_(0.5)(m-phda)]·0.5H_2O}_n(1),{[Cd_2(btbb)(adtda)_2(H_2O)]·H_2O}_n(2),[Mn_2(btbb)(tbi)_2]_n(3),{[Cd(btbb)_(0.5)(3-Nitro-o-bdc)(H_2O)]·H_2O}_n(4)和[Cd_2(btbb)(tbi)_2]_n(5)(btbb=1,4-双(2-(4-噻唑基)苯并咪唑-1-基甲基)苯,m-H_2phda=间苯二甲酸,H_2adtda=1,3-金刚烷二羧酸,H_2tbi=5-叔丁基间苯二甲酸,3-Nitro-o-H_2bdc=3-硝基-1,2-苯二甲酸)。配合物1是一个包含22元环的一维链。配合物2是一个包含8元环的一维链,并且氮配体在这个一维链中仅仅起到装饰作用。配合物3是一个一维双链结构。配合物4是一个包含14元环的一维链。配合物5是一个阶梯状的一维双链结构。
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| 关 键 词： | 配合物 半刚性配体 羧酸 晶体结构 |
| 收稿时间： | 2018-12-10 |
| 修稿时间： | 2019-03-03 |
Syntheses, Characterization and Crystal Structures of Five 1D Complexes Based on Semi-rigid Bis(thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers |
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| LIU Lu,JIN Ping-Ning,LI Ying,LOU Hui-Hui,WANG Jian-Ji,ZHANG Yu-Ping,HOU Hong-Wei and DU Jin-Ge. Syntheses, Characterization and Crystal Structures of Five 1D Complexes Based on Semi-rigid Bis(thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers[J]. Chinese Journal of Inorganic Chemistry, 2019, 35(6): 1076-1084 |
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| Authors: | LIU Lu JIN Ping-Ning LI Ying LOU Hui-Hui WANG Jian-Ji ZHANG Yu-Ping HOU Hong-Wei DU Jin-Ge |
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| Affiliation: | School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China,Xinxiang Medical University, Xinxiang, Henan 453000, China,School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China,School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China,School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China,School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China,College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, China and Department of Chemistry, Sanquan College of Xinxiang Medical University, Xinxiang, Henan 453003, China |
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| Abstract: | Five coordination complexes, formulated as {[Zn(btbb)0.5(m-phda)]·0.5H2O}n (1), {[Cd2(btbb)(adtda)2(H2O)]·H2O}n (2),[Mn2(btbb)(tbi)2]n (3), {[Cd(btbb)0.5(3-Nitro-o-bdc)(H2O)]·H2O}n (4) and[Cd2(btbb)(tbi)2]n (5) (btbb=1,4-bis(2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene, m-H2phda=m-phenylenediacetic acid, H2adtda=1,3-adaman-tanedicarboxylic acid, H2tbi=5-tert-butylisophthalic acid, 3-Nitro-o-H2bdc=3-Nitro-1,2-benzenedicarboxylic acid), have been obtained by hydro(solv)thermal reactions and structurally characterized. Complex 1 exhibits a 1D chain structure containing 22-membered rings. Complex 2 features a 1D chain structure having an 8-membered rings and btbb serves only as an ornament here. Complex 3 is a 1D double chain structure. Complex 4 possesses a 1D chain structure containing 14-membered rings. Complex 5 shows a 1D double chain taking on stair-step. |
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| Keywords: | complex semi-rigid ligand carboxylate crystal structure |
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