| 二氧化钛基Z型异质结光催化剂 |
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| 引用本文： | 梅邱峰,张飞燕,王宁,鲁闻生,宿新泰,王伟,武荣兰.二氧化钛基Z型异质结光催化剂[J].无机化学学报,2019,35(8):1321-1339. |
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| 作者姓名： | 梅邱峰 张飞燕 王宁 鲁闻生 宿新泰 王伟 武荣兰 |
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| 作者单位： | 新疆大学化学化工学院石油天然气精细化工重点实验室;中国科学院化学研究所胶体界面与化学热力学重点实验室;华南理工大学环境与能源学院工业聚集区污染控制与生态修复教育部重点实验室 |
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| 基金项目： | 国家自然科学基金（No.21868036）和新疆维吾尔自治区自然科学基金（No.2016D01C037）资助项目。 |
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| 摘 要： | 二氧化钛(TiO_2)因廉价、无毒、化学性质稳定以及具有较强的光催化氧化还原能力,在光催化领域占据着重要的地位。然而,可见光利用率低以及光生电子-空穴对的快速复合是限制其应用的2个主要因素。二氧化钛基Z型异质结作为一种新型光催化剂,既改善了二氧化钛的2个缺陷,又表现出比TiO_2更强的氧化或还原能力。本文概括了TiO_2光催化剂、异质结光催化剂和TiO_2基Z型光催化剂的能带排列和电子传递原则,探讨了Z型异质结和type-Ⅱ异质结的异同点以及区分方法,并归纳总结了TiO_2基Z型异质结在光催化领域中的应用。
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| 关 键 词： | 二氧化钛 Z型异质结 type-Ⅱ异质结 多相催化 环境化学 水分解 二氧化碳还原 |
| 收稿时间： | 2019/4/5 0:00:00 |
| 修稿时间： | 2019/5/28 0:00:00 |
Photocatalysts: Z-Scheme Heterojunction Constructed with Titanium Dioxide |
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| MEI Qiu-Feng,ZHANG Fei-Yan,WANG Ning,LU Wen-Sheng,SU Xin-Tai,WANG Wei and WU Rong-Lan.Photocatalysts: Z-Scheme Heterojunction Constructed with Titanium Dioxide[J].Chinese Journal of Inorganic Chemistry,2019,35(8):1321-1339. |
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| Authors: | MEI Qiu-Feng ZHANG Fei-Yan WANG Ning LU Wen-Sheng SU Xin-Tai WANG Wei and WU Rong-Lan |
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| Institution: | Key Laboratory of Oil & Gas Fine Chemicals, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China,Key Laboratory of Oil & Gas Fine Chemicals, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China,Key Laboratory of Oil & Gas Fine Chemicals, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China,Key Laboratory of Colloids, Interfaces and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100086, China,Key Laboratory of Oil & Gas Fine Chemicals, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China;Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters(Ministry of Education), School of Environment and Energy of South China University of Technology, Guangzhou 510006, China,Key Laboratory of Oil & Gas Fine Chemicals, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China and Key Laboratory of Oil & Gas Fine Chemicals, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China |
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