| 锌镍单液流电池正极Ni1-xMnx(OH)2倍率性能分析 |
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| 引用本文： | 姚寿广,窦飞,邢如月,程杰,肖民. 锌镍单液流电池正极Ni1-xMnx(OH)2倍率性能分析[J]. 无机化学学报, 2019, 35(8): 1403-1410 |
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| 作者姓名： | 姚寿广 窦飞 邢如月 程杰 肖民 |
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| 作者单位： | 江苏科技大学能源与动力学院;张家港智电芳华蓄电研究所有限公司;浙江裕源储能科技有限公司 |
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| 基金项目： | 国家自然科学基金（No.51776092）资助项目。 |
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| 摘 要： | 采用缓冲溶液法制备Mn掺杂Ni_(1-x)Mn_x(OH)_2(x=0.1,0.2,0.3,0.4)。X射线衍射(XRD)测试表明x=0.1和0.2的样品主要是由β相组成;扫描电子显微镜(SEM)和氮气吸附-脱附测试表明掺杂Mn样品比不掺Mn的商用β-Ni(OH)2的颗粒更细小、多孔;恒流充放电测试表明,这种电极具有优良的高倍率性能,当x=0.2,电流密度800 mA·g-1时放电比容量为288.8 mAh·g-1,同等条件测试的商用β-Ni(OH)2放电比容量为198.7 mAh·g-1,循环580圈后仍有276 mAh·g-1的放电比容量,其衰减率为4.1%,而同等测试条件下的其它4种样品衰减率分别为46.1%(商用β-Ni(OH)2)、13.0%(x=0.1)、25.6%(x=0.3)、34.1%(x=0.4),可见这种Mn掺杂电极材料适合大电流密度充放电,能够改善镍电极的循环稳定性,降低镍电极成本。
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| 关 键 词： | 缓冲溶液法 Ni1-xMnx(OH)2 倍率性能 循环稳定性 |
| 收稿时间： | 2019-03-30 |
| 修稿时间： | 2019-06-30 |
Rate Performance Analysis of Ni1-xMnx(OH)2 as Cathode Material for Zinc-Nickel Single Flow Battery |
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| YAO Shou-Guang,DOU Fei,XING Ru-Yue,CHENG Jie and XIAO Min. Rate Performance Analysis of Ni1-xMnx(OH)2 as Cathode Material for Zinc-Nickel Single Flow Battery[J]. Chinese Journal of Inorganic Chemistry, 2019, 35(8): 1403-1410 |
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| Authors: | YAO Shou-Guang DOU Fei XING Ru-Yue CHENG Jie XIAO Min |
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| Affiliation: | School of Energy and Power Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China,School of Energy and Power Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China;Zhangjiagang Smartgrid Fanghua Electrical Energy Storage Research Institute Co., Ltd., Suzhou, Jiangsu 215600, China,School of Energy and Power Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China;Zhangjiagang Smartgrid Fanghua Electrical Energy Storage Research Institute Co., Ltd., Suzhou, Jiangsu 215600, China,Zhangjiagang Smartgrid Fanghua Electrical Energy Storage Research Institute Co., Ltd., Suzhou, Jiangsu 215600, China;Zhejiang Yuyuan Energy Storage Technology Co., Ltd., Huzhou, Zhejiang 313100, China and School of Energy and Power Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China |
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| Abstract: | |
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| Keywords: | buffer solution method Ni1-xMnx(OH)2 rate performance cyclic stability |
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