| 摘 要： | Mn-based Heusler alloys have attracted significant research attention as half-metallic materials because of their giant magnetocr.ystalline anisotropy and magnetocaloric properties.We investigate the crystal structure and magnetic properties of polycrystalline,[101]-oriented,and[100]-oriented Mn_(2-δ) Sn prepared separately by arc melting,the Bridgeman method,and the flux method.All of these compounds crystallize in a Ni_2 In-type structure.In the Mn_(2-δ)Sn lattice,Mn atoms occupy all of the 2 a and a fraction of the 2 d sites.Site disorder exists between Mn and Sn atoms in the 2 c sites.In addition,these compounds undergo a re-entrant spin-glass-like transition at low temperatures,which is caused by frustration and randomness within the spin system.The magnetic properties of these systems depend on the crystal directions,which means that the magnetic interactions differ significantly along different directions.Furthermore,these materials exhibit a giant magnetocaloric effect near the Curie temperature.The largest value of maximum of magnetic entropy change(-△S_M)occurs perpendicular to the[100]direction.Specifically,at 252 K,maximum-△S_M is 2.91 and 3.64 J-kg~(-1)K~(-1) for a magnetic field of 5 and7 T,respectively.The working temperature span over 80 K and the relative cooling power reaches 302 J/kg for a magnetic field of 7 T,which makes the Mn_(2-δ)Sn compound a promising candidate for a magnetic refrigerator.
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