Structure of products of the reaction of 2-cyanoaziridine with carbonyl compounds期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Structure of products of the reaction of 2-cyanoaziridine with carbonyl compounds

Authors:	K. F. Koehler H. Zaddach G. K. Kadorkina V. N. Voznesenskii I. I. Chervin R. G. Kostyanovsky

Affiliation:	(1) Kampfstoffen, Kampfstoffmunition, Barbarahof, Gesellschaft für Beseitigung von Kampfmitteln, Kreutzen 17, D-3042 Munster, Germany;(2) N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977 Moscow, Russian Federation

Abstract:	The structure of azimexone (3), the product of the reaction of 2-cyanoaziridine with acetone, was confirmed on the basis of¹H and¹³C NMR spectra. The formation of this product is accounted for by the -aziridinoalkylating action of an intermediate containing a good leaving iminoyloxy group. Similar reactions were observed for 1-chloromethylaziridine and a 1-aziridinylmethylammonium salt (6), but not for 1-methoxymethylaziridine (7) and 1-aziridinemethanol.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2136–2139, December, 1993.

Keywords:	2-(2-cyanoaziridino)-2-(2-carbamoylaziridino)propane l-tert-butyl-2-carbamoylaziridine /content/k1825406673w125m/xxlarge945.gif" alt=" agr" align=" BASELINE" BORDER=" 0" >-1-aziridinoalkylation ¹H and¹³C NMR spectra
本文献已被 SpringerLink 等数据库收录！