In situ formed white-light-emitting lanthanide-zinc-organic frameworks |
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Authors: | Li Shu-Mu Zheng Xiang-Jun Yuan Da-Qiang Ablet Ayjamal Jin Lin-Pei |
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Institution: | College of Chemistry, Beijing Normal University, Beijing 100875, People's Republic of China. |
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Abstract: | Five novel 3D heterometallic lanthanide-zinc-organic frameworks, H(H(2)O)(8)]LnZn(4)(imdc)(4)(Him)(4)] Ln = La (1), Pr (2), Eu (3), Gd (4), Tb (5); H(3)imdc = 4,5-imidazoledicarboxylic acid; Him = imidazole], were synthesized via an in situ hydrothermal reaction, and tunable luminescence from yellow to white was obtained through the doping of Eu and Tb ions in the La-Zn framework. |
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