On the Pressure and Electric Field Dependencies of the Relative Permittivity of Liquids期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

On the Pressure and Electric Field Dependencies of the Relative Permittivity of Liquids

Authors:	Yizhak Marcus Glenn Hefter

Institution:	(1) Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem, 91904, Israel;(2) Chemistry Department, Murdoch University, Murdoch, WA, 6150, Australia

Abstract:	The dependencies of the relative permittivity of over 50 liquids on the pressure P, as $(\partial \ln \varepsilon /P)_{T,P^0 }$ , and of some 40 liquids on the (square of the) electric field E at ambient conditions, as ${\beta } = \partial \varepsilon /\partial (E^2 )]_{T,P^0 }$ were obtained from literature data. The function $(\partial \ln \varepsilon /P)_{T,P^0 }$ was fitted to a simple expression in and the compressibility, _T. These data were used to obtain the limiting slope for the partial molar volumes and the electrostriction of electrolytes in various solvents.

Keywords:	Electric field electrolyte volumes electrostriction pressure relative permittivity
本文献已被 SpringerLink 等数据库收录！