Nitrosyl derivatives of group VI metals containing monodentate amines |
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Authors: | Dhruva N Pathak |
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Institution: | (1) Department of Chemistry, M. L. K. College, 271201 Balrampur, U.P., India |
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Abstract: | Summary Passage of a slow stream of nitric oxide through a benzene solution of M(CO)5(Am), (M = Mo and W; Am = BuNH2, C6H11NH2, PhCH2NH2, C5H11N, C5H5N and BuNO) yielded dimeric M(NO)3(Am)]2 complexes which have been characterized by elemental analysis, magnetic data and i.r. spectra. The i.r. data indicate the presence of terminal as well as of bridging nitric oxide in the complexes. |
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