Reaction of α-cyanoacrylic acid catalyzed by tertiary amines |
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| Authors: | I. I. Kandror I. O. Bragina M. A. Galkina B. D. Lavrukhin Yu. G. Gololobov |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | The action of pyridine on a-cyanoacrylic add leads to the rapid and quantitative formation of 2,4-dicyano-4-pentenoic add. In the presence of excess p-nitro-benzaldehyde, 1-hydroxy-1-p-nitrophenyl-2-cyano-2-butene is formed in this reaction in addition to 2,4-dicyano-4-pentenoic add.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2644–2646, November, 1989. |
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