Temperature-dependent interactions and disorder in the spin-transition compound [Fe(II)(L)2][ClO4]2.C7H8 through structural, calorimetric, magnetic, photomagnetic, and diffuse reflectance investigations |
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Authors: | Mishra Vibha Mukherjee Rabindranath Linares Jorge Balde Chérif Desplanches Cédric Létard Jean-François Collet Eric Toupet Loic Castro Miguel Varret François |
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Institution: | GEMAC, CNRSUniversite de Versailles, 78035 Versailles cedex, France. |
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Abstract: | The title compound Fe (II)(L) 2]ClO 4] 2.C 7H 8 (L = 2-3-(2'-pyridyl)pyrazol-1-ylmethyl]pyridine) has been isolated while attempting to grow single crystals of the spin-transition (continuous-type) compound Fe (II)(L) 2]ClO 4] 2, published earlier ( Dalton Trans. 2003, 3392-3397). Magnetic susceptibility measurements, as well as Mossbauer and calorimetric investigations on polycrystalline samples of Fe(L) 2]ClO 4] 2.C 7H 8 revealed the occurrence of an abrupt HS ( (5) T 2) <--> LS ( (1) A 1) transition with steep and narrow (2 K) hysteresis at approximately 232 K. The photomagnetic properties exhibit features typical for a broad distribution of activation energies, with relaxation curves in the shape of stretched exponentials. We performed a crystal structure determination of the compound at 120, 240, and 270 K. A noteworthy temperature-dependent behavior of the structural parameters was observed, in terms of disorder of both the anions and solvent molecules, leading to a strong thermal dependence of the strength and dimensionality of the interaction network. Additional data were obtained by diffuse reflectance measurements. We model and discuss the antagonistic effects of interactions and disorder by using a two-level cooperative mean-field approach which includes a distribution of barrier energies at the microscopic scale. |
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