Cobalt(III) tetrabenzoporphyrin: Synthesis,spectral and coordination properties |
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| Authors: | G M Mamardashvili N V Chizhova E Yu Kaigorodova N Zh Mamardashvili |
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| Institution: | 1.Krestov Institute of Solution Chemistry,Russian Academy of Sciences,Ivanovo,Russia |
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| Abstract: | Comparison of tetrabenzoporphyrin complexation reactions and transmetalation of cadmium(II) tetrabenzoporphyrinate with cobalt(II) acetate and chloride in dimethylformamide (DMF) has been carried out Cobalt(III) tetrabenzoporphyrinate has been prepared and identified. Acido ligands displacement in Co(III) tetrabenzoporphyrinate by pyridine, imidazole, and quinuclidine molecules has been studied. |
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