Formation of heteropolynuclear cobalt(II) and nickel(II) complexonates with EDTA and 2-aminopropanoic acid |
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Authors: | V I Kornev G F Alabdulla T N Kropacheva E V Batueva |
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Institution: | 1.Udmurt State University,Izhevsk,Russia |
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Abstract: | Coordination equilibria in the Co(II)–Ni(II)–2-aminopropanoic acid (HAla)–EDTA system have been studied spectrophotometrically at different molar ratios of the reagents in a wide pH range. It has been found that, when metal ions are in excess with respect to EDTA at pH 5–9, polyheteronuclear complexonates (CoAla)Edta(NiAla)]2–, (CoAla2)Edta(NiAla2)]4–, (NiAla2)Edta(CoAla2)2]4–, (CoAla2)Edta(NiAla2)2]4–, and (NiAla2)2Edta(CoAla2)2]4– form in a solution. The equilibrium constants of formation of these complexes and their overall stability constants have been calculated. Possible structures of the polynuclear complexonates are discussed. |
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