Thermodynamic functions of arsenic selenides |
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| Authors: | D M Babanly G M Velieva S Z Imamaliyeva M B Babanly |
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| Institution: | 1.Baku Institute of Catalysis and Inorganic Chemistry,Azerbaijan National Academy of Sciences,Baku,Azerbaijan;2.Baku State University,Baku,Azerbaijan |
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| Abstract: | The solid-phase equilibria and thermodynamic properties of an As–Se system are studied using the electromotive force (EMF). The existence of compounds As2Se3, AsSe, and As4Se3 in a system with near constant composition is confirmed. The relative partial molar functions, standard Gibbs free energies, enthalpies of formation, and standard entropies of As in the alloys are calculated using EMF measurements. |
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