KBaR(BO3)2 orthoborates (R = REE): Synthesis and study |
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| Authors: | V. S. Shevchenko N. G. Kononova A. E. Kokh A. K. Bolatov B. M. Uralbekov M. M. Burkitbaev |
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| Affiliation: | 1.Sobolev Institute of Geology and Mineralogy, Siberian Branch,Russian Academy of Sciences,Novosibirsk,Russia;2.Al-Farabi Kazakh National University,Almaty,Kazakhstan |
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| Abstract: | The search for compounds with the formula composition KBaR(BO3)2 has been performed by solid-phase synthesis and differential thermal analysis. The compounds synthesized in this series are KBaPr(BO3)2 and KBaNd(BO3)2, which are isostructural to KBaY(BO3)2, are isotypical to butschliite K2Ca(CO3)2, and crystallize in a trigonal system with space group R3m. The structural characteristics of compounds calculated for the entire series of REEs are given. |
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