Onium salts of sulfur-containing oxyanions resulting from reaction of sulfur(IV) oxide with aqueous solutions of 1,2-diamines and morpholine |
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| Authors: | R. E. Khoma V. O. Gel’mbol’dt A. A. Ennan V. N. Baumer A. N. Puzan T. V. Koksharova A. V. Mazepa |
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| Affiliation: | 1.Physicochemical Institute for Environment and Human Protection,National Academy of Sciences of Ukraine,Odessa,Ukraine;2.Odessa National University,Odessa,Ukraine;3.Odessa National Medical University,Odessa,Ukraine;4.Institute of Single Crystals,National Academy of Sciences of Ukraine,Kharkov,Ukraine;5.Bogatskii Physicochemical Institute,National Academy of Sciences of Ukraine,Odessa,Ukraine |
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| Abstract: | Reaction products have been isolated from SO2–L–H2O–О2 systems (L = ethylenediamine, N,N,N′,N′-tetramethylethylenediamine, piperazine, and morpholine) as onium salts [H3NCH2CH2NH3]SO4, [(CH3)2NHCH2CH2NH(CH3)2]SO4, [(CH3)2NHCH2CH2NH(CH3)2]S2O6 ? H2O, [C4H8N2H4]SO3 ? H2O, [C4H8N2H4]S2O6, [C4H8N2H4]SO4 ? H2O, [O(C2H4)2NH2]2SO4 ? H2O. The prepared compounds have been characterized by X-ray diffraction analysis, X-ray powder diffraction, IR and mass spectroscopy. |
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