Effect of anomalously slow motions of particles with spins of 1/2 on the shape of the magnetic resonance line of pairs of particles |
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Authors: | A I Shushin V P Sakun |
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Institution: | (1) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia |
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Abstract: | A non-Markovian version of the Liouville stochastic equation was used to analyze spin relaxation in a pair of particles with spins 1/2 and the dipole-dipole interaction between the spins. The particles were involved in anomalously slow stochastic relative rotation described by the angular correlation function K(t) ~ 1/t α with α < 1. The Liouville stochastic equation could be used to describe memory effects in the kinetic dependence of rotational relaxation resulting in a very slow descent of K(t). Our analysis showed that the anomalous relative motion of radicals manifested itself in special features of the shape of the magnetic resonance line of the particle pair. |
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