A modular approach to catalyst hydrophobicity for an asymmetric aldol reaction in a biphasic aqueous environment |
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| Authors: | Lombardo Marco Easwar Srinivasan De Marco Alessandro Pasi Filippo Trombini Claudio |
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| Institution: | Dipartimento di Chimica G. Ciamician, Università di Bologna, via Selmi 2, Bologna, Italy. marco.lombardo@unibo.it |
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| Abstract: | Catalyst 5, an ion pair consisting of a hydrophilic cation and a lipophilic anion, fulfils the solubility requirements needed to couple efficiency (enantioselectivities and anti-diastereoselectivities up to > or = 99%) and catalyst recyclability in asymmetric aldol reactions under aqueous biphasic conditions. |
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