Design and characterization of [(Et)3 N-H]FeCl4 as a nanomagnetic ionic liquid catalyst for the synthesis of xanthene derivatives under solvent-free conditions
1.Department of Chemistry, Central Tehran Branch, Islamic Azad University Tehran, Tehran, Iran ;
Abstract:
The triethylamine-based nanomagnetic ionic liquid, [(Et)3 N-H]FeCl4, was synthesized, and its structural and chemical characteristics were detected. The thermogravimetric analysis indicated its high thermal stability with a decomposition temperature higher than 300 °C. Additionally, [(Et)3 N-H]FeCl4 was used to efficiently catalyze the synthesis of xanthene derivatives under solvent-free conditions at 120 °C. [(Et)3 N-H]FeCl4 was recycled and reused at least five times.